VAPOR-LIQUID EQUILIBRIA FOR BINARY AND TERNARY SYSTEMS CONTAINING CARBON DIOXIDE

Molecular model for carbon dioxide optimized to vapor-liquid equilibria.

A molecular model for carbon dioxide is presented, and the parameters of the Lennard-Jones sites, the bond length, and the quadrupole moment are optimized to experimental vapor-liquid equilibrium data. The resulting molecular model shows mean unsigned deviations to the experiment over the whole temperature range from triple point to critical point of 0.4% in saturated liquid density, 1.8% in va...

Prediction of Liquid-Liquid Equilibria of Binary Systems Containing Alcohols Using EoS-GE Models

Binary Vapor-liquid Equilibria of Carbon Dioxide-light Hydrocarbons at Low Temperature*

light hydrocarbons at low temperatures is of interest in the design of the proper equipment to make such separations. In the previous paper4) of this series, the equilibrium relationships for two binary mixtures of carbon dioxide with ethylene and ethane at 0°C have been described. Those for the ethylene and ethsine binaries with carbon dioxide have been shown to form, minimum-boiling azeotrope...

Determination of Binary Vapor Liquid Equilibria (vle) of Reactive Systems

The simulation of reactive distillation processes requires binary phase equilibrium data and information about the reaction kinetics and equilibrium. The phase equilibrium data for the binary reacting sub-systems are difficult to measure experimentally since the products of reaction affect the binary equilibrium as soon as they are formed. A novel apparatus has been constructed to measure these...

Group Contribution Method for Predicting the Phase Behavior of Binary Mixtures Containing Carbon Dioxide